UV curing-assisted 3D plotting of ceramic feedstock containing thermo-regulated phase-separable,photocurable vehicle for dual-scale porosity structure

We propose a novel approach for manufacturing dual-scale porosity alumina structures by UV curing-assisted 3D plotting of a specially formulated alumina feedstock using a thermo-regulated phase separable, photocurable camphene/triethylene glycol dimethacrylate (TEGDMA) vehicle. In particular, 3D plotting process was conducted at - 5 °C, and thus an alumina suspension prepared using liquid camphene/TEGDMA at room temperature could undergo phase separation, resulting in camphene crystals surrounded by walls comprised of liquid photopolymer enclosing alumina particles. To enhance the shape retention ability of extruded filaments, polystyrene (PS) polymer was used as the tackifier. The phase-separated feedrod could be extruded favorably through a nozzle and rapidly photopolymerized by UV light during the 3D plotting process. Three-dimensionally interconnected macropores were tightly constructed, which were separated by microporous alumina filaments, where micropores were created by the removal of camphene crystals via freeze-dying. The macroporosity of porous alumina ceramics was controlled by adjusting the distance between deposited filaments, while their microporosity was kept constant, leading to tightly tailored overall porosity and mechanical properties.     

Annealing temperature dependent structural and optical properties of electrodeposited CdSe thin films

Cadmium selenide films were synthesized using simple electrodeposition method on indium tin oxide coated glass substrates. The synthesized films were post annealed at 200 °C, 300 °C and 400 °C. X-ray diffraction of the films showed the hexagonal structure with crystallite size <3 nm for as deposited films and 3–25 nm for annealed films. The surface morphology of films using field emission scanning electron microscopy showed granular surface. The high resolution transmission electron microscopy of a crystallite of the film revealed lattice fringes which measured lattice spacing of 3.13 Å corresponding to (002) plane, indicating the lattice contraction effect, due to small size of CdSe nanocrystallite. The calculation of optical band gap using UV–visible absorption spectrum showed strong red-shift with increase in crystallite size, indicating to the charge confinement in CdSe nanocrystallite.     

Transparent and flexible films of new segmented polyurethane nanocomposites incorporated by NH2-functionalized TiO2 nanoparticles

In this work, TiO₂ nanoparticles are surface modified by NH₂-terminated organic moieties arised from 4,4′-methylene diphenyl diisocyanate (MDI). These nanoparticles are incorporated into ether-based segmented polyurethane (SPU) matrix. MDI is utilized as monomer together with poly(tetramethylene oxide) (PTMO) comonomer for preparing the final polymer as well. The NH₂-functionalized TiO₂ nanoparticles are covalently linked to the NCO terminals of the resulting SPU macromolecules during film preparation stage. Therefore, in addition to butylene glycol, these surface modified nanoparticles with enhanced organophilicity could play the role of the second chain extender of NCO-capped SPU macromolecules through formation of urea linkages. Optical and thermal behaviors of the transparent and flexible film (SPU/TiO₂–MDI) is compared with those of unmodified TiO₂ (SPU/TiO₂) and TiO₂-unloaded SPU films. Though the particle loading is only 5 wt.%, incorporation of TiO₂ and TiO₂–MDI nanoparticles into the SPU polymer enhances significantly the light absorption in UV region at 300–400 nm. SEM images of the prepared films clearly show a considerable decrease in particle aggregation for TiO₂–MDI into SPU matrix compared to that of unmodified TiO₂. TG analyses indicate a one-step decomposition pattern with onset temperatures of about 360 and 380 °C for neat SPU and SPU/TiO₂–MDI, respectively. Moreover, DTA thermograms of both nanocomposites show obviously two exothermic phase transitions in the thermal range of 330–440 °C.     

减振器在自导系统结构设计中的应用

通过对减振器结构设计的理论分析，建立了减振器的数学模型，同时通过设计的模拟装置对减振效果进行了实测，效果良好。     

医用聚氯乙烯材料的表面光接枝改性

研究了在不排氧氛围下 ,紫外光照射 ,以二苯甲酮 (BP)为光引发剂 ,甲基丙烯酸缩水甘油酯(GMA)在医用聚氯乙烯 (PVC)薄膜表面的气相接枝聚合。探讨了反应条件对接枝结果的影响 ,并用正交法指出了影响因素的显著性。用傅立叶红外 (FT- IR)、水接触角作为接枝改性结果的表征。FT- IR谱图表明 GMA已接枝到 PVC膜表面。水接触角由接枝前的 78°下降到 5 4°     

分子束外延生长液晶光阀用ZnSxSe1-x薄膜的研究

描述了ZnSxSe1-x光盲紫外液晶光阀的结构和工作原理 ,并从器件的电学模型出发 ,着重讨论了整体器件对ZnSxSe1-x光敏层的特殊要求。采用分子束外延技术在ITO导电玻璃上制备了具有 (111)面定向生长结构的ZnSxSe1-x多晶薄膜 ,通过控制反应时的生长参数 ,制备出了符合器件设计要求的光敏层薄膜。室温下 ,该薄膜的紫外 /可见光响应对比度大于10 3 ;响应波长截止边可通过控制薄膜中的Se组分 ,在 (36 0～ 4 10 )nm范围内连续可调 ;薄膜的暗电阻率在 (4 32× 10 9～ 2 0 3×10 11)Ω·m之间 ,并随着晶粒的增大而减小 ;在液晶光阀工作的低频段 (<2 0 0Hz) ,其光 /暗阻抗比在 0 2 2～ 0 36之间。     

将紫外光谱用于溴指数测定方法的选择

对未知组成的样品进行紫外光谱扫描 ,根据扫描结果以及各种溴指数测定方法的适用范围 ,选择测定未知物溴指数的适宜方法 ,以提高测定准确度。     

Performance of natural‐fiber–plastic composites under stress for outdoor applications: Effect of moisture,temperature, and ultraviolet light exposure

The effects of moisture, temperature, and ultraviolet (UV) light on performance of natural‐fiber–plastic composites (NFPC) were assessed. We conducted short‐term tests in the laboratory and long‐term tests under natural exposure and measured changes in mechanical properties and color in samples of the composite. Chemical changes of the composite's materials were measured by X‐ray photoelectron spectroscopy to elucidate the mechanisms of chemical transformations on the material surface. Relative humidity highly affected the modulus of rupture (MOR) and the modulus of elasticity (MOE), and had a greater effect than temperature and UV exposure on performance of the composite. The lightness of the composite was increased by the UV effect in the short‐ and the long‐term tests. The X‐ray photoelectron spectroscopy (XPS) analysis suggested that the composite was protected by the UV absorber. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 2570–2577, 2006     

基于光敏自组装多层膜的液晶光控取向膜

采用layer-by-layer(LBL)的方法，将基板依次在具有光敏双键的季铵盐水溶液和聚乙烯基苯磺酸钠水溶液中浸泡，石英基板表面形成了自组装多层沉积膜。经线性偏振紫外光辐照后，LBL多层膜表现出明显的紫外吸收各向异性。将两片带有各向异性薄膜的基板做成平行液晶器件。在正交的偏光显微镜下观察，发现取得均一、稳定的取向效果。该种光控取向膜有望用作LCoS微显示的取向层。     

垂直管吸收器内泡式吸收过程的数值研究

建立垂直管吸收器管内泡式吸收过程中传热传质的数学物理模型，对其泡式吸收过程进行数值研究，获得泡式吸收方式的一些传热传质特性，为吸收器的优化设计提供一定理论指导。